Champions League predictions - 21 October 2025, Round 3
This article provides expert predictions for the upcoming Round 3 of the Champions League matches. Borussia Dortmund, in fine form, is expected to secure a solid win against Copenhagen. A tightly contested match is predicted between PSV and Napoli, with potential for a 1-1 draw. Inter Milan, riding high after winning their first two UCL matches, looks poised to dominate against Union Saint-Gilloise. Manchester City, unbeaten in their last eight games, is expected to win narrowly against Villarreal. Each game presents its own potential twists and highlights.
- Copenhagen to go down heavily to Dortmund.
- PSV to fight hard to beat Napoli at home.
- Inter to batter the Union Saint-Gilloise goalmouth.
- Man City to win against a plucky Villareal.

Erling Haaland attacks the Monaco goal.
(credit: Jonathan Moscrop/Getty Images)
Champions League Predictions, Round 3
- Champions League Predictions, Round 3
- Copenhagen vs Borussia Dortmund
- PSV vs Napoli
- Union Saint-Gilloise vs Inter Milan
- Villarreal vs Manchester City
Copenhagen vs Borussia Dortmund
Copenhagen are winless in the Champions League and will have to battle hard for a point against 7th-placed Dortmund. They are having a mediocre season in the Danish Superliga, while Dortmund are looking strong in the Bundesliga, with a 13:6 goal spread. In their last game they pushed Bundesliga powerhouse Bayern Munich hard, losing 2-1, and in the Champions League they beat Atletico Bilbao 4-1 and drew 4-4 with Juventus. Dortmund should claim a win by three clear goals.
PSV vs Napoli
Both teams have three wins in their last five matches. PSV’s other two games were draws, while Napoli have suffered two losses, including their last match (1-0 to Torino). Neither side is fat with goals, so this should be a tight game, although Napoli have been weaker away from home in recent weeks. Probably a 2-1 home win will be reported in the Wednesday morning papers, but don’t be surprised if it’s a 1-1 draw.
Union Saint-Gilloise vs Inter Milan
Inter are looking strong this season, winning their opening two Champions League matches with a 5-0 combined scoreline. Saint-Gilloise had a good away win over PSV, only to be hammered 4-0 at home by Newcastle, losing two of their last three games. Inter have won six of their last seven games and have been scoring freely this season… so Saint-Gilloise will be challenged at the back.
Villarreal vs Manchester City
City are undefeated in their last eight matches, winning six, drawing two and scoring 18:4. Villareal have won just three of their last nine matches, and their last win was four matches ago. They held Juventus 2-2 at home, so they won’t be pushovers and will likely park the bus and look for breakaway goals against City. The visitors are in such good form I don’t see them failing to beat Villareal, although it’s likely to be a 1-0 or 2-1 win for City.
Verdict
In-form Dortmund to give Copenhagen headaches at the back, while PSV and Napoli to play out a draw.
Inter to pound Saint-Gilloise, while Man City will have to fight hard for three points against Villareal.
Inter to pound Saint-Gilloise, while Man City will have to fight hard for three points against Villareal.
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